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प्रश्न
How do you prepare:
Actinoid elements show wide range of oxidation states.
Account for the following:
Actinoid elements show wide range of oxidation states.
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उत्तर
Actinides exhibit larger oxidation states because of the very small energy gap between 5f, 6d and 7s sub-shells. The energies are calculated on the basis of the (n + l) rule. The (n + l) values of the three orbitals are:
5f = 5 + 3 = 8
6d = 6 + 2 = 8
7s = 7 + 0 = 7
Since all the values are almost the same, therefore all orbitals can be involved in bonding resulting in a larger oxidation number for actinoids.
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संबंधित प्रश्न
Distinguish between lanthanoid and actinoids.
How would you account for the following:
The chemistry of actinoids is more complicated as compared to lanthanoids.
How would you account for the following:
Actinoid contraction is greater than lanthanoid contraction.
Why do actinoids show a wide range of oxidation states?
Write on similarity between the chemistry of lanthanoids and actinoids.
Which is the last element in the series of the actinoids? Write the electronic configuration of this element. Comment on the possible oxidation state of this element.
There are 14 elements in actinoid series. Which of the following elements does not belong to this series?
Which of the following actinoids show oxidation states upto +7?
(i) Am
(ii) Pu
(iii) U
(iv) Np
Assertion: Actinoids form relatively less stable complexes as compared to lanthanoids.
Reason: Actinoids can utilise their 5f orbitals along with 6d orbitals in bonding but lanthanoids do not use their 4f orbital for bonding.
Why do actinoids show variable oxidation states?
