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Fluorine shows only –1 oxidation state while other halogens show –1, +1, +3, +5 and +7 oxidation states. Explain. - Chemistry

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प्रश्न

Fluorine shows only –1 oxidation state while other halogens show –1, +1, +3, +5 and +7 oxidation states. Explain.

Explain why fluorine shows only –1 oxidation state while other halogens show higher positive oxidation state?

स्पष्ट कीजिए
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उत्तर

  1. The fluorine atom has no d-orbitals in its valence shell and therefore, cannot expand its octet. Thus, fluorine is the most electronegative exhibit –1 oxidation state only.
  2. Cl, Br, and I exhibit –1, +1, +3, +5, and +7 oxidation states. This is because they are less electronegative than F and possess empty d-orbitals in the valence shell and therefore, can expand the octet.
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अध्याय 7: Elements of Groups 16, 17 and 18 - Short Answer Questions (Type-II)

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
अध्याय 7 Elements of Groups 16, 17 and 18
Short Answer Questions (Type-II) | Q 2.1
बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 7 Elements of Groups 16, 17 and 18
Exercises | Q 3. vii. | पृष्ठ १६४

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