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प्रश्न
Explain with reason sign conventions of ΔS in the following reaction
CO2(g) → CO2(g)
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उत्तर
CO2(g)→CO2(g)
The entropy of the system decrease because disorder decreases.
ΔS is negative
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संबंधित प्रश्न
Face centred cubic crystal lattice of copper has density of 8.966 g.cm-3. Calculate the volume of the unit cell. Given molar mass of copper is 63.5 g mol-1 and Avogadro number NA is 6.022 x 1023 mol-1
An element with molar mass 27 g mol−1 forms a cubic unit cell with edge length 4.05 ✕ 10−8 cm. If its density is 2.7 g cm−3, what is the nature of the cubic unit cell?
Distinguish between Hexagonal and monoclinic unit cells
Distinguish between Face-centred and end-centred unit cells.
How can you determine the atomic mass of an unknown metal if you know its density and the dimension of its unit cell? Explain.
Explain with reason sign conventions of ΔS in the following reaction
N2(g) + 3H2(g) → 2NH3(g)
A face centred cube (FCC) consists of how many atoms? Explain
An element has atomic mass 93 g mol−1 and density 11.5 g cm–3. If the edge length of its unit cell is 300 pm, identify the type of unit cell. (NA = 6.023 × 1023 mol−1)
The density of silver having an atomic mass of 107.8 g mol- 1 is 10.8 g cm-3. If the edge length of cubic unit cell is 4.05 × 10- 8
cm, find the number of silver atoms in the unit cell.
( NA = 6.022 × 1023, 1 Å = 10-8 cm)
What is the total number of atoms per unit cell in a face-centered cubic structure?
An atom located at the body center of a cubic unit cell is shared by ____________.
Volume of unit cell occupied in face-centered cubic arrangement is ____________.
TiCl has the structure of CsCl. The coordination number of the ions in TiCl is ____________.
A substance forms face-centered cubic crystals. Its density is 1.984 g/cm3 and the length of the edge of the unit cell is 630 pm. Calculate the molar mass in g/mol?
Sodium metal crystallises in a body-centred cubic lattice with a unit cell edge of 4.29 Å. The radius of the sodium atom is approximately ______.
The empty space in the body-centered cubic lattice is ____________.
The number of atoms contained in a fcc unit cell of a monoatomic substance is ____________.
Which of the following metal(s) show(s) hexagonal close-packed structure (hcp) and which show face-centered cubic (fcc) structure?
The density of a metal which crystallises in bcc lattice with unit cell edge length 300 pm and molar mass 50 g mol−1 will be:
An element with atomic mass 100 has a bcc structure and edge length 400 pm. The density of element is:
Match the type of unit cell given in Column I with the features given in Column II.
| Column I | Column II |
| (i) Primitive cubic unit cell | (a) Each of the three perpendicular edges compulsorily have the different edge length i.e; a ≠ b ≠ c. |
| (ii) Body centred cubic unit cell | (b) Number of atoms per unit cell is one. |
| (iii) Face centred cubic unit cell | (c) Each of the three perpendicular edges compulsorily have the same edge length i.e; a = b = c. |
| (iv) End centred orthorhombic cell | (d) In addition to the contribution from unit cell the corner atoms the number of atoms present in a unit cell is one. |
| (e) In addition to the contribution from the corner atoms the number of atoms present in a unit cell is three. |
The coordination number for body center cubic (BCC) system is
The correct set of quantum numbers for 2p sub shell is:
Percentage of free space in body centred cubic unit cell is
An element A (Atomic weight = 100) having bcc structure has a unit cell edge length 400 pm. The number of atoms in 10 g of A is ______ × 1022 unit cells.
The ratio of number of atoms present in a simple cubic, body-centred cubic and face-centred cubic structure are, respectively ______.
