Advertisements
Advertisements
प्रश्न
A 0.1 m solution of K2SO4 in water has a freezing point of –4.3°C. What is the value of van’t Hoff factor if Kf for water is 1.86 K kg mol–1?
Advertisements
उत्तर
Given: Molality of K2SO4 solution = m = 0.1 m
Freezing point of solution = Tf = – 4.3 °C
Kf of water = 1.86 K kg mol–1
To find: van’t Hoff factor
Formula: ΔTf = i Kfm
Calculation:
ΔTf = `"T"_"f"^0` – Tf
= 0 °C – (–4.3 °C) = 4.3 °C = 4.3 K
Now, using the formula,
ΔTf = i Kf.m
∴ i = `(Δ"T"_"f")/("K"_"f"."m")`
`= (4.3 "K")/(1.86 "k kg mol"^-1 xx 0.1 "mol kg"^-1)`
= 23.11
The value of van’t Hoff factor is 23.11.
APPEARS IN
संबंधित प्रश्न
Answer the following in one or two sentences.
What is van’t Hoff factor?
Answer the following in one or two sentences.
How is van’t Hoff factor related to degree of ionization?
Answer the following in one or two sentences.
Which of the following solution will have higher freezing point depression and why?
i. 0.1 m NaCl
ii. 0.05 m Al2(SO4)3
Derive the relationship between the degree of dissociation of an electrolyte and van’t Hoff factor.
A 0.15 m aqueous solution of KCl freezes at - 0.510 °C. Calculate i and osmotic pressure at 0 °C. Assume the volume of solution equal to that of water.
Calculate van't Hoff-factor for 0.2 m aqueous solution of KCl which freezes at - 0.680°C. (Kf = 1.86 K kg mol-1).
If the van't Hoff-factor for 0.1 M Ba(NO3)2 solution is 2.74, the degree of dissociation is ______.
0.6 g of a solute is dissolved in 0.1 L of a solvent which develops an osmotic pressure of 1.23 atm at 27°C. The molecular mass of the solute is ______.
Relationship between van't Hoff's factor (i) and degree of dissociation (α) is ______.
If van't Hoff factor of monofluoroacetic acid in water is 1.076. What is it's degree of dissociation?
Which of the following equation is correct to determine osmotic pressure using van't Hoff equation?
Van't Hoff factor for K3[Fe(CN)6] is 3.333. What is it's percentage dissociation in water?
Why is observed molar mass of acetic acid in benzene is greater than actual molar mass?
Solution of 'A' containing 1.73 g of it in 100 cm3 of water is found to be isotonic with a 3.42% (w/v) solution of sucrose. The molecular weight of A is ______. (At. mass C = 12, H = 1, 0 = 16)
0.01 m aqueous formic acid solution freezes at – 0.021°C. Calculate its degree of dissociation, Kf = 1.86 K kg mol–1.
The equation that represent general van't Hoff equation is ______.
Write modification of expressions of colligative properties with the help of van't Hoff factor.
Calculate the van't Hoff factor assuming the complete dissociation of NaBr in its aqueous solution.
Calculate ΔTb and boiling point of 0.05 m aqueous solution of glucose. (Given: Kb = 0.52 K m−1).
The value of van't Hoff factor will be minimum for ______.
For 1 molal aqueous solution of the following compounds, which one will show the highest freezing point?
The depression in freezing point of 0.2 m aqueous solution of an electrolyte is 0.7 K. Calculate its percent degree of dissociation. [Kf for water = 1.86 K kg mol-1; n = 2]
