Topic: Chemical Thermodynamics and Energetic
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Chemical Thermodynamics and Energetic
- Concepts of system, types of systems, surroundings.
- Work, heat, energy, extensive and intensive properties, state functions.
- First law of thermodynamics – internal energy and enthalpy, Hess’ law of constant heat summation, enthalpy of bond dissociation, combustion, formation, atomization, sublimation. Phase transition, ionization and solution and dilution Introduction of entropy as a state function, free energy change for spontaneous and non spontaneous processes, and equilibrium constant.
- Second and third law of thermodynamics