Tamil Nadu Board of Secondary EducationHSC Science Class 11th

# Tamil Nadu Board Samacheer Kalvi solutions for Class 11th Chemistry Volume 1 and 2 Answers Guide chapter 9 - Solutions [Latest edition]

## Chapter 9: Solutions

Choose the best answer [Pages 61 - 64]

### Tamil Nadu Board Samacheer Kalvi solutions for Class 11th Chemistry Volume 1 and 2 Answers Guide Chapter 9 SolutionsChoose the best answer [Pages 61 - 64]

Choose the best answer | Q I. 1. | Page 61

The molality of a solution containing 1.8 g of glucose dissolved in 250 g of water is

• 0.2 M

• 0.01 M

• 0.02 M

• 0.04 M

Choose the best answer | Q I. 2. | Page 61

Which of the following concentration terms is/are independent of temperature

• molality

• molarity

• mole fraction

• molality and molarity

Choose the best answer | Q I. 3. | Page 61

Stomach acid, a dilute solution of HCl can be neutralized by reaction with aluminium hydroxide $\ce{Al(OH)3 + 3HCl (aq) -> AlCl3 + 3H2O}$

How many milliliters of 0.1 M Al(OH)3 solution is needed to neutralize 21 ml of 0.1 M HCl?

• 14 mL

• 7 mL

• 21 mL

• none of these

Choose the best answer | Q I. 4. | Page 61

The partial pressure of nitrogen in air is 0.76 atm and its Henry’s law constant is 7.6 × 104 atm at 300 K. What is the mole fraction of nitrogen gas in the solution obtained when air is bubbled through water at 300 K?

• 1 × 10-4

• 1 × 104

• 2 × 10-5

• 1 × 10-5

Choose the best answer | Q I. 5. | Page 61

Henry’s law constant for the solubility of Nitrogen gas in water at 350 K is 8 × 104 atm. The mole fraction of nitrogen in air is 0.5. The number of moles of Nitrogen from air dissolved in 10 moles of water at 350 K and 4 atm pressure is

• 4 × 10-4

• 4 × 104

• 2 × 10-2

• 2.5 × 10-4

Choose the best answer | Q I. 6. | Page 61

Which one of the following is incorrect for an ideal solution?

• ∆Hmix = 0

• ∆Umix = 0

• ∆P = "P"_"observed"  -  "P"_"calculated by Raoults law" = 0

• ∆Gmix = 0

Choose the best answer | Q I. 7. | Page 61

Which one of the following gases has the lowest value of Henry’s law constant?

• N2

• He

• CO2

• H2

Choose the best answer | Q I. 8. | Page 62

P1 and P2 are the vapour pressures of pure liquid components, 1 and 2 respectively of an ideal binary solution If x1 represents the mole fraction of component 1, the total pressure of the solution formed by 1 and 2 will be

• P1 + x1 (P2 – P1)

• P2 – x1 (P2 + P1)

• P1 – x2(P1 – P2)

• P1 + x2(P1 – P2)

Choose the best answer | Q I. 9. | Page 62

Osomotic pressure (π) of a solution is given by the relation

• π = nRT

• πV = nRT

• πRT = n

• none of these

Choose the best answer | Q 10. | Page 62

Which one of the following binary liquid mixtures exhibits positive deviation from Raoults law?

• Acetone + chloroform

• Water + nitric acid

• HCl + water

• ethanol + water

Choose the best answer | Q I. 11. | Page 62

The Henry’s law constants for two gases A and B are x and y respectively. The ratio of mole fractions of A to B 0.2. The ratio of mole fraction of B and A dissolved in water will be

• (2x)/"y"

• "y"/(0.2 x)

• (0.2 x)/"y"

• (5x)/"y"

Choose the best answer | Q I. 12. | Page 62

At 100°C the vapour pressure of a solution containing 6.5g a solute in 100g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be

• 102°C

• 100°C

• 101°C

• 100.52°C

Choose the best answer | Q I. 13. | Page 62

According to Raoults law, the relative lowering of vapour pressure for a solution is equal to ______.

• mole fraction of solvent

• mole fraction of solute

• number of moles of solute

• number of moles of solvent

Choose the best answer | Q I. 14. | Page 62

At same temperature, which pair of the following solutions are isotonic?

• 0.2 M BaCl2 and 0.2 M urea

• 0.1 M glucose and 0.2 M urea

• 0.1 M NaCl and 0.1 M K2SO4

• 0.1 M Ba(NO3)2 and 0.1 M Na2SO4

Choose the best answer | Q I. 15. | Page 62

The empirical formula of a nonelectrolyte(X) is CH2 O. A solution containing six gram of X exerts the same osmotic pressure as that of 0.025M glucose solution at the same temperature. The molecular formula of X is

• C2H4O2

• C8H16O8

• C4H8O4

• CH2O

Choose the best answer | Q I. 16. | Page 62

The KH for the solution of oxygen dissolved in water is 4 × 104 atm at a given temperature. If the partial pressure of oxygen in air is 0.4 atm, the mole fraction of oxygen in solution is ______.

• 4.6 × 103

• 1.6 × 104

• 1 × 10-5

• 1 × 105

Choose the best answer | Q I. 17. | Page 62

Normality of 1.25M sulphuric acid is ______.

• 1.25 N

• 3.75 N

• 2.5 N

• 2.25 N

Choose the best answer | Q I. 18. | Page 62

Two liquids X and Y on mixing gives a warm solution. The solution is ______.

• ideal

• non-ideal and shows positive deviation from Raoults law

• ideal and shows negative deviation from Raoults Law

• non-ideal and shows negative deviation from Raoults Law

Choose the best answer | Q I. 19. | Page 63

The relative lowering of vapour pressure of a sugar solution in water is 2.5 × 10-3. The mole fraction of water in that solution is ______.

• 0.0035

• 0.35

• 0.0035/18

• 0.9965

Choose the best answer | Q I. 20. | Page 63

The mass of a non – volatile solute (molar mass 80 g mol-1) should be dissolved in 92g of toluene to reduce its vapour pressure to 90% ______.

• 10 g

• 20 g

• 9.2 g

• 8 g

Choose the best answer | Q I. 21. | Page 63

For a solution, the plot of osmotic pressure (π) versus the concentration (c in mol L-1) gives a straight line with slope 310 R where ‘R’ is the gas constant. The temperature at which osmotic pressure measured is ______.

• 310 × 0.082 K

• 310° C

• 37°C

• 310/0.082K

Choose the best answer | Q I. 22. | Page 63

200 ml of an aqueous solution of a protein contains 1.26 g of protein. At 300 K, the osmotic pressure of this solution is found to be 2.52 × 10-3 bar. The molar mass of protein will be (R = 0.083 L bar mol-1 K-1)

• 62.22 kg mol-1

• 12444 g mol-1

• 300 g mol-1

• None of these

Choose the best answer | Q I. 23. | Page 63

The Van't Hoff factor (i) for a dilute aqueous solution of the strong elecrolyte barium hydroxide is (NEET) ______.

• 0

• 1

• 2

• 3

Choose the best answer | Q I. 24. | Page 63

Which is the molality of a 10% w/w aqueous sodium hydroxide solution?

• 2.778

• 2.5

• 10

• 0.4

Choose the best answer | Q I. 25. | Page 63

The correct equation for the degree of an associating solute, ‘n’ molecules of which undergoes association in solution, is

• α = ("n"("i" - 1))/("n - 1")

• α2 = ("n"(1 - "i"))/("n - 1")

• α = ("n"("i" - 1))/("1 - n")

• α = ("n"(1 - "i"))/("n"("1 - i"))

Choose the best answer | Q I. 26. | Page 63

Which of the following aqueous solutions has the highest boiling point?

• 0.1 M KNO3

• 0.1 M Na3PO4

• 0.1 M BaCl2

• 0.1 M K2SO4

Choose the best answer | Q I. 27. | Page 63

The freezing point depression constant for water is 1.86° K Kg mol-1. If 5 g Na2SO4 is dissolved in 45 g water, the depression in freezing point is 3.64°C. The Vant Hoff factor for Na2SO4 is ______.

• 2.57

• 2.63

• 3.64

• 5.50

Choose the best answer | Q I. 28. | Page 63

Equimolal aqueous solutions of NaCl and KCl are prepared, If the freezing point of NaCl is -2°C, the freezing point of KCl solution is expected to be ______.

• -2°C

• -4°C

• -1°C

• 0°C

Choose the best answer | Q I. 29. | Page 63

Phenol dimerizes in benzene having van’t Hoff factor 0.54. What is the degree of association?

• 0.46

• 92

• 46

• 0.92

Choose the best answer | Q I. 30. | Page 64

Assertion: An ideal solution obeys Raoults Law.

Reason: In an ideal solution, solvent – solvent as well as solute – solute interactions are similar to solute-solvent interactions.

• Both assertion and reason are true and reason is the correct explanation of assertion

• Both assertion and reason are true but reason is not the correct explanation of assertion.

• Assertion is true but reason is false

• Both assertion and reason are false

Write brief answer to the following questions. [Page 64]

### Tamil Nadu Board Samacheer Kalvi solutions for Class 11th Chemistry Volume 1 and 2 Answers Guide Chapter 9 SolutionsWrite brief answer to the following questions. [Page 64]

Write brief answer to the following questions. | Q II. 1. (i) | Page 64

Define molality.

Write brief answer to the following questions. | Q II. 1. (ii) | Page 64

Define Normality.

Write brief answer to the following questions. | Q II. 2. | Page 64

What is a vapour pressure of liquid?

Write brief answer to the following questions. | Q II. 2. | Page 64

What is a relative lowering of vapour pressure?

Write brief answer to the following questions. | Q II. 3. | Page 64

State and explain Henry’s law.

Write brief answer to the following questions. | Q II. 4. | Page 64

State Raoult law and obtain the expression for lowering of vapour pressure when the nonvolatile solute is dissolved Insolvent.

Write brief answer to the following questions. | Q II. 5. | Page 64

What is molal depression constant? Does it depend on nature of the solute?

Write brief answer to the following questions. | Q II. 6. | Page 64

What is osmosis?

Write brief answer to the following questions. | Q II. 7. | Page 64

Define isotonic solutions

Write brief answer to the following questions. | Q II. 8. | Page 64

You are provided with a solid ‘A’ and three solutions of A dissolved in water – one saturated, one unsaturated, and one super saturated. How would you determine each solution?

Write brief answer to the following questions. | Q II. 9. | Page 64

Explain the effect of pressure on solubility.

Write brief answer to the following questions. | Q II. 10. | Page 64

A sample of 12 M Concentrated hydrochloric acid has a density 1.2 M gL-1 calculate the molality.

Write brief answer to the following questions. | Q II. 11. | Page 64

A 0.25 M glucose solution, at 370.28 K has approximately the pressure as blood does what is the osmotic pressure of blood?

Write brief answer to the following questions. | Q II. 12. | Page 64

Calculate the molality of a solution containing 7.5 g glycine(NH2-CH2-COOH) dissolved in 500g of water.

Write brief answer to the following questions. | Q II. 13. | Page 64

Which solution has the lower freezing point? 10 g of methanol (CH3OH) in 100g g of water (or) 20 g of ethanol (C2H5OH) in 200 g of water.

Write brief answer to the following questions. | Q II. 14. | Page 64

How many moles of solute particles are present in one liter of 10-4 M potassium sulphate?

Write brief answer to the following questions. | Q II. 15. | Page 64

Henry’s law constant for solubility of methane in benzene is 4.2 × 10-5 mm Hg at a particular constant temperature. At this temperature calculate the solubility of methane at

1. 750 mm Hg
2. 840 mm Hg.
Write brief answer to the following questions. | Q II. 16. | Page 64

The observed depression in the freezing point of water for a particular solution is 0.093°C calculate the concentration of the solution in molality. Given that molal depression constant for water is 1.86 K Kg mol-1.

Write brief answer to the following questions. | Q II. 17. | Page 64

The vapour pressure of pure benzene (C6H6) at a given temperature is 640 mm Hg. 2.2 g of non – volatile solute is added to 40 g of benzene. The vapour pressure of the solution is 600 mm Hg. Calculate the molar mass of the solute?

## Tamil Nadu Board Samacheer Kalvi solutions for Class 11th Chemistry Volume 1 and 2 Answers Guide chapter 9 - Solutions

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Concepts covered in Class 11th Chemistry Volume 1 and 2 Answers Guide chapter 9 Solutions are Abnormal Molar Masses, Solutions, Types of Solutions, Expressing Concentration of Solutions, Solubility of the Solutes, Henry's Law, Vapour Pressure of Liquid Solutions - Introduction, Vapour Pressure of Liquid, Ideal and Non-ideal Solutions, Colligative Properties, Reverse Osmosis (RO).

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