University of Mumbai Syllabus For Semester 5 (TE Third Year) Thermodynamics and Biochemical Engineering: Knowing the Syllabus is very important for the students of Semester 5 (TE Third Year). Shaalaa has also provided a list of topics that every student needs to understand.

The University of Mumbai Semester 5 (TE Third Year) Thermodynamics and Biochemical Engineering syllabus for the academic year 2022-2023 is based on the Board's guidelines. Students should read the Semester 5 (TE Third Year) Thermodynamics and Biochemical Engineering Syllabus to learn about the subject's subjects and subtopics.

Students will discover the unit names, chapters under each unit, and subtopics under each chapter in the University of Mumbai Semester 5 (TE Third Year) Thermodynamics and Biochemical Engineering Syllabus pdf 2022-2023. They will also receive a complete practical syllabus for Semester 5 (TE Third Year) Thermodynamics and Biochemical Engineering in addition to this.

## University of Mumbai Semester 5 (TE Third Year) Thermodynamics and Biochemical Engineering Revised Syllabus

University of Mumbai Semester 5 (TE Third Year) Thermodynamics and Biochemical Engineering and their Unit wise marks distribution

### University of Mumbai Semester 5 (TE Third Year) Thermodynamics and Biochemical Engineering Course Structure 2022-2023 With Marking Scheme

# | Unit/Topic | Weightage |
---|---|---|

100 | Basic Concepts | |

200 | Laws of Thermodynamics | |

300 | PVT Behaviour | |

400 | Biochemical Energetics | |

500 | Properties of Pure Fluids | |

600 | Fugacity and Activity | |

700 | Properties of Solutions | |

800 | Phase Equilibria | |

Total | - |

## Syllabus

- System
- Surrounding & Processes
- Closed and Open systems
- State and Properties
- Intensive & Extensive Properties
- State and Path functions
- Equilibrium state and Phase rule
- Zeroth law of Thermodynamics
- Heat reservoir and Heat engines
- Reversible and Irreversible processes

- General statement of First law of Thermodynamics
- First law for Cyclic Process
- Non-Flow Process
- Flow process
- Heat capacity
- General statements of the second law
- Concept of entropy
- The Carnot principle
- Calculation of entropy changes
- Clausius inequality
- Entropy and Irreversibility
- Third law of Thermodynamics

- PVT behaviour of pure fluids
- equations of state and ideal gas law
- Processes involving ideal gas law: Constant volume, constant pressure constant temperature, adiabatic and polytrophic processes.
- Equations of state for real gases: Van-der Waals equation, Redlich- Kwong equation, Peng-Robinson equation, virial equation.

- Coupled reactions and energy rise compounds
- Reaction Stoichiometry
- criteria of biochemical reaction equilibrium
- equilibrium constant and standard free energy change
- effect of temperature
- pressure on free energy change
- effect of temperature
- pressure on equilibrium constants and other- factors affecting equilibrium conversion.
- Le Chateliers principle
- liquid phase reactions
- heterogeneous bioreaction equilibria
- phase rule for reacting systems

- Principles of corresponding states
- Generalized compressibility charts
- Reference properties
- energy properties
- Derived properties
- Helmholtz free energy
- Gibbs free energy
- Relationships among thermodynamic Properties:-
- Exact differential equations
- fundamental property relations
- Maxwell’s equations
- Clapeyron equations
- Entropy heat capacity relations
- modified equations for internal energy (U) & enthalpy (H)
- Effect of temperature on U
- H & Entropy (S)
- Relationships between Cp & Cv
- Gibbs- Helmholtz equation

- Fugacity
- Fugacity coefficient
- effect of temperature and pressure on fugacity
- Determination of fugacity of pure gases
- Fugacities of solids and liquids
- Activity: Effect of temperature and pressure on activity
- Departure functions and generalized charts
- thermodynamic diagrams types of diagrams and construction of thermodynamic diagrams

- Partial molar properties of solutions
- determination of partial molar properties
- chemical potential effect of temperature and pressure
- lewis randall rule
- Raoults law for ideal solutions
- Henry’s law and dilute solutions ideal behavior of real solutions and Henrys law
- Activity in solutions
- Activity coeffi- cients effect of temperature and pressure
- Gibbs - Duhem equation
- Property changes of mixing
- excess properties excess Gibbs free energy.

- Criteria of phase Equilibria
- criterion of stability
- Duhem’s theorem
- Vapour-Liquid Equilibria
- VLE in ideal solutions
- Non-Ideal solutions -
- azeotropes
- VLE at low pressures activity co efficient equation
- bubble point and dew point equilibria
- Consistency test for VLE data using slope of ln ? curves
- using partial pressure data
- calculation of activity coefficients using Gibbs - Duhem equation
- Liquid-Liquid Equilibrium diagrams binary liquid Equilibrium diagrams