BE Chemical Engineering Semester 4 (SE Second Year)University of Mumbai

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Engineering Chemistry 2 Semester 4 (SE Second Year) BE Chemical Engineering University of Mumbai Topics and Syllabus

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CBCGS [2017 - current]
CBGS [2013 - 2016]
Old [2000 - 2012]

Topics with syllabus and resources

100.00 Electrochemistry
  • Conductance, specific conductance, equivalent conductance, molar conductance.
  • Effect of dilution and temperature on conductance.
  • Transport number.
  • DebyeHuckel theory of strong electrolytes.
  • Concentration cells with and without transference w.r.t. cations.
  • Standard cells.
  • Use of EMF measurement and other technique for determination of solubility product, hydrogen ion concentration.
200.00 Instrumental Methods of Analysis
201.00 Conductometry
  • Principle and types of titrations - Acid-base, precipitation and complexometric
202.00 Potentiometry
  • Principle and types of titrations - Acid-base, precipitation and complexometric.
203.00 Amperometry Polarography
  • Methods and applications
204.00 Chromatography
  • Adsorption and partition.
  • Study of Paper Chromatography, Thin Layer Chromatography, High Performance Liquid Chromatography, Gas (Liquid and solid)
  • Chromatography –Principle and their applications.
205.00 Optical Methods
  • (Principle, Instrumentation and applications) UV, IR, NMR, GC-MS spectroscopy, flame photometry.
300.00 Ion Exchange and Solvent Extraction Techniques
  • Ion exchange resins, cation and anion exchangers.
  • Desalination by ion exchange and separation of lanthanides.
  • Solvent extraction. Nernst distribution law.
  • Distribution ratio.
  • Batch, continuous and counter current extraction.
  • Numericals based on solvent extraction.
400.00 Colloids and Surfactants
  • Origin of charge on colloidal particles.
  • Concept of electrical double layer.
  • Helmholtzand system models. Electro-kinetic PhenomenonElectrophoresis, electro-osmosis, streaming potential and Dorn effect (Sedimentation potential).
  • Colloidal electrolytes, Donnam Membrane equilibrium Colloidal electrolytes.
  • Emulsions O/Wand W/O types, emulsifying agents, surfactants.
  • Applications of surfactants in detergents, pesticide formulations and food industry.
500.00 Industrially Important Esters and Aromaticity
  • Synthesis and properties of malonic ester and aceto acetic ester
  • Aromaticity and aromatic character, Huckel’s rule of aromaticity, Aromatic character of Benzene, Naphthalene, Anthracene,Pyrrole, Furan, Thiophene, Pyridine.
600.00 Catalysis
  • Definition
  • Criteria of catalysis
  • Types (Homogeneous and Heterogeneous)
  • Catalytic promoters, poisons.
  • Negative catalysis and inhibition.
  • Autocatalysis and Induced catalysis.
  • Activation energy and catalysis.
  • Intermediate compound formation theory.
  • Adsorption theory.
  • Acid-Base catalysis and mechanism.
  • Enzyme catalysis.
  • Characteristics and mechanism of enzyme catalysis.
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