University of Mumbai Syllabus For Semester 3 (SE Second Year) Engineering Chemistry 1: Knowing the Syllabus is very important for the students of Semester 3 (SE Second Year). Shaalaa has also provided a list of topics that every student needs to understand.
The University of Mumbai Semester 3 (SE Second Year) Engineering Chemistry 1 syllabus for the academic year 2022-2023 is based on the Board's guidelines. Students should read the Semester 3 (SE Second Year) Engineering Chemistry 1 Syllabus to learn about the subject's subjects and subtopics.
Students will discover the unit names, chapters under each unit, and subtopics under each chapter in the University of Mumbai Semester 3 (SE Second Year) Engineering Chemistry 1 Syllabus pdf 2022-2023. They will also receive a complete practical syllabus for Semester 3 (SE Second Year) Engineering Chemistry 1 in addition to this.
University of Mumbai Semester 3 (SE Second Year) Engineering Chemistry 1 Revised Syllabus
University of Mumbai Semester 3 (SE Second Year) Engineering Chemistry 1 and their Unit wise marks distribution
University of Mumbai Semester 3 (SE Second Year) Engineering Chemistry 1 Course Structure 2022-2023 With Marking Scheme
# | Unit/Topic | Weightage |
---|---|---|
100 | Basic Concepts of Chemistry and Molecular Structures | |
200 | Co-ordination Chemistry | |
300 | Organometallic Compounds and Bio-inorganic Chemistry | |
400 | Reaction Mechanism and Reactive Intermediates | |
500 | Reactive Intermediates | |
600 | Substitution Reactions | |
Total | - |
Syllabus
- Hydrogen bonding, Valence bond-Theory, Molecular orbital theory, Non-bonding and anti-bonding orbitals, LCAO method, VSEPR theory.
- Structure of BF3, PCl3, PCl5 and SF4.
- Molecular orbital structures of homonuclear and heteronuclear molecules H2, BF2, B2, C2, N2, O2, F2, CO, HF, NO2, metallic bond.
- Co-ordination number or ligancy, Complex ion, Co-ordination dative bond complexions.
- Theories of coordination compounds such as Werner’s Co-ordination theory, Valence bond-Theory, Crystal field theory (CFT), Ligand field theory.
- Effective Atomic Number (EAN).
- Nomenclature and isomerism (Only Geometrical and Structural) in co-ordination compounds with respect to co-ordination number 4 and 6.
- Application of CFT to tetrahedral and octahedral complexes, drawbacks of CFT, MOT as applied to octahedral complexes of Fe, Measurement of CFSE (10Dq), Numericals based on EAN and 10Dq measurement, Applications of coordination compounds.
- Chemistry of Fe-carbonyls with respect to preparation, properties, structure and bonding.
- Biochemistry of proteins containing Cu, Fe and Zn chemistry of cytochromes and their application, O2 atom transfer reactions of biomolecules containing Fe.
- Transition state (T.S.), Intermediate.
- Difference between T.S. & intermediate.
- Equilibrium (Thermodynamically) controlled & rate (Kinetically) controlled reactions.
- Explain w.r.t. Nitration of chlorobenzene, methylation of toluene by Friedel-Craft’s reaction, sulphonation of naphthalene.
- Reactive intermediates
- Carbocation, carbanion, carbon free radicals and carbenes – their formation, structure & stability.
- Name reactions with mechanism w.r.t. each reactive intermediate.
- Carbocation – Pinacol - Pinacolone reaction.
- Carbanion – Michael reaction.
- Free radical - Wohl-Ziegler bromaination reaction.
- Carbene - Reimer-Tiemann reaction for aldehyde.
1. Electrophilic substitution reactions
- In monocyclic aromatic compounds
- Mechanism
- Orientation influence
- Friedel Craft alkylation
2. Nucleohilic substitution reactions
- SN1 reaction with mechanism
- SN2 reaction with mechanism
3. Elimination reactions
- E1 reaction with mechanism
- E2 reaction with mechanism