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Why is Wurtz Reaction Not Preferred for the Preparation of Alkanes Containing Odd Number of Carbon Atoms? Illustrate Your Answer by Taking One Example - Chemistry

Why is Wurtz reaction not preferred for the preparation of alkanes containing odd number of carbon atoms? Illustrate your answer by taking one example

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Solution 1

Wurtz reaction is limited for the synthesis of symmetrical alkanes (alkanes with an even number of carbon atoms) In the reaction, two similar alkyl halides are taken as reactants and an alkane, containing double the number of carbon atoms, are formed. Example:

Wurtz reaction cannot be used for the preparation of unsymmetrical alkanes because if two dissimilar alkyl halides are taken as the reactants, then a mixture of alkanes is obtained as the products. Since the reaction involves free radical species, a side reaction also occurs to produce an alkene. For example, the reaction of bromomethane and iodoethane gives a mixture of alkanes.

The boiling points of alkanes (obtained in the mixture) are very close. Hence, it becomes difficult to separate them

Solution 2

For preparation of alkanes containing odd number of carbon atoms, a mixture of two alkyl halides has to be used. Since two alkyl halides can react in three different ways, therefore, a mixture of three alkanes instead of the desired alkane would be formed. For example, Wurtz reaction between ‘1-bromopropane and 1-bromobutane gives a mixture of three alkanes i.e., hexane, heptane and octane as shown below:

Concept: Alkenes - Preparation of Alkenes from Alkynes, Alkyl Halides, Vicinal Dihalides and Alcohols by Acidic Dehydration
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NCERT Class 11 Chemistry Textbook
Chapter 13 Hydrocarbons
Q 25 | Page 397
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