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What Are Electron Deficient Compounds? Are Bcl3 and Sicl4 Electron Deficient Species? Explain - Chemistry

What are electron deficient compounds? Are BCl3 and SiCl4 electron deficient species? Explain

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Solution 1

In an electron-deficient compound, the octet of electrons is not complete, i.e., the central metal atom has an incomplete octet. Therefore, it needs electrons to complete its octet.

(i) BCl3

BCl3 is an appropriate example of an electron-deficient compound. B has 3 valence electrons. After forming three covalent bonds with chlorine, the number of electrons around it increases to 6. However, it is still short of two electrons to complete its octet.

(ii) SiCl4

The electronic configuration of silicon is ns2 np2. This indicates that it has four valence electrons. After it forms four covalent bonds with four chlorine atoms, its electron count increases to eight. Thus, SiCl4 is not an electron-deficient compound.

Solution 2

Electron deficient species are those in which the central atom in their molecule has the tendency to accept one or more electron pairs. They are also known as Lewis acid. BCl3 and  SiCl4 both are electron deficient species

Since, in BCl3, B atom has only six electrons. Therefore, it is an electron deficient compound.
In SiCl4 the central atom has 8 electrons but it can expand its covalency beyond 4 due to the presence of d-orbitals.
Thus, SiCl4 should also be considered as electron deficient species.

Concept: Important Trends and Anomalous Properties of Boron
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NCERT Class 11 Chemistry Textbook
Chapter 11 The p-Block Elements
Q 9 | Page 324
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