The work function for caesium atom is 1.9 eV. Calculate (a) the threshold wavelength and (b) the threshold frequency of the radiation. If the caesium element is irradiated with a wavelength 500 nm, calculate the kinetic energy and the velocity of the ejected photoelectron.
Solution
It is given that the work function (W0) for caesium atom is 1.9 eV.
(a) From the expression, `W_0 = (hc)/lambda_0`, we get
`lambda_0 = (hc)/W_0`
Where,
λ0 = threshold wavelength
h = Planck’s constant
c = velocity of radiation
Substituting the values in the given expression of (λ0):
`lambda_0 = ((6.626 xx 10^(-34)Js)(3.0xx10^8 ms^(-1)))/(1.9xx1.602 xx 10^(-19) J)`
`lambda_0 = 6.53 xx 10^(-7) m`
Hence, the threshold wavelength `lambda_0` is 653 nm.
(b) From the expression, `W_0 = hv_0` we get:
`v_0 = W_0/h`
Where
ν0 = threshold frequency
h = Planck’s constant
Substituting the values in the given expression of ν0:
v_0 = (1.9xx1)
ν0 = threshold frequency
h = Planck’s constant
Substituting the values in the given expression of ν0:
`v_0 = (1.9xx1.602xx10^(-19)J)/(6.626xx10^(-34)Js)`
(1 eV = 1.602 × 10–19 J)
ν0 = 4.593 × 1014 s–1
Hence, the threshold frequency of radiation (ν0) is 4.593 × 1014 s–1.
(c) According to the question:
Wavelength used in irradiation (λ) = 500 nm
Kinetic energy = h (ν – ν0)
`= hc(1/lambda - 1/lambda_0)`
`= (6.626 xx 10^(-34) Js) (3.0 xx 10^8 ms^(-1)) ((lambda_0 - lambda)/(lambdalambda_0))`
`= (1.9878 xx 10^(-26) Jm) [((653 - 500)10^(-9)m)/((653)(500)10^(-18)m^2)]`
`= ((1.9878 xx 10^(-26))(153xx10^9))/((653)(500))J`
= 9.3149 × 10–20 J
Kinetic energy of the ejected photoelectron = 9.3149 × 10–20J
Since `K.E = 1/2 mv^2 = 9.3149 xx 10^(-20) J`
`v = sqrt((2(9.3149 xx 10^(-20)J))/(9.10939 xx 10^(-31) kg))`
`= sqrt(2.0451 xx 10^11 m^2s^(-2))`
Hence, the velocity of the ejected photoelectron (v) is 4.52 × 105 ms–1