Answer 1

Carbon monoxide is highly-poisonous because of its ability to form a complex with haemoglobin. The CO–Hb complex is more stable than the O₂–Hb complex. The former prevents Hb from binding with oxygen. Thus, a person dies because of suffocation on not receiving oxygen. It is found that the 
CO–Hb complex is about 300 times more stable than the O₂–Hb complex.

Answer 2

CO reacts with haemoglobin to form carboxyhaemoglobin which can destroy the oxygen carrying capacity of haemoglobin and the man dies of suffocation.