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Solution for Differentiate Between the Principle of Estimation of Nitrogen in an Organic Compound By Kjeldahl’S Method. - CBSE (Science) Class 11 - Chemistry

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Question

Differentiate between the principle of estimation of nitrogen in an organic compound by Kjeldahl’s method.

Solution 1

In Kjeldahl’s method, a known quantity of nitrogen containing organic compound is heated with concentrated sulphuric acid. The nitrogen present in the compound is quantitatively converted into ammonium sulphate. It is then distilled with excess of sodium hydroxide. The ammonia evolved during this process is passed into a known volume of H2SO4. The chemical equations involved in the process are

`(NH_4)_2SO_4  + 2NaOH -> Na_2SO_4 + 2NH_3 + 2H_2O`

`2NH_3 + H_2SO_4 -> (NH_4)_2 SO_4`

The acid that is left unused is estimated by volumetric analysis (titrating it against a standard alkali) and the amount of ammonia produced can be determined. Thus, the percentage of nitrogen in the compound can be estimated. This method cannot be applied to the compounds, in which nitrogen is present in a ring structure, and also not applicable to compounds containing nitro and azo groups.

Solution 2

Kjeldahl’s method: A known mass of the organic compound is heated strongly with cone. H2SO4, a little potassium sulphate and a little mercury (a catalyst). As a result of reaction the nitrogen present in the organic compound is converted to ammonium sulphate.

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APPEARS IN

 NCERT Chemistry Textbook for Class 11 Part 2 (with solutions)
Chapter 12: Organic Chemistry - Some Basic Principles and Techniques
Q: 22.2 | Page no. 363
Solution for question: Differentiate Between the Principle of Estimation of Nitrogen in an Organic Compound By Kjeldahl’S Method. concept: Quantitative Analysis of Nitrogen. For the course CBSE (Science)
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