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Write the Equations Involved in the Following Reactions : Williamson Synthesis - Chemistry

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ConceptPreparation of Ethers from Dehydration of Alcohols and Williamson Systhesis

Question

Write the equations involved in the following reactions : Williamson synthesis

Solution 1

Williamson synthesis: It involves the treatment of an alkyl halide with a suitable sodium alkoxide. The sodium alkoxide needed for the purpose is prepared by the action of sodium on a suitable alcohol. The reaction invlolves the nucleophillic displacement (substitution) of the halide ion from the alkyl halide by the alkoxide ion by SN2 mechanism.

R-OH +2Na → 2R’-O-Na+ + H2

R’-O-Na+ + R-X → R’-O-R +Na+ X

                            Ether

The second reaction is the substitution nucleophillic bimolecular (SN2) reaction.

For example:

Solution 2

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Solution Write the Equations Involved in the Following Reactions : Williamson Synthesis Concept: Preparation of Ethers from Dehydration of Alcohols and Williamson Systhesis.
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