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Solution - Physical and Chemical Properties of Alcohols and Phenols

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Question

How are the following conversions carried out?

Methyl magnesium bromide → 2-Methylpropan-2-ol.

Solution

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Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses. Explain this fact.

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Give reasons for the following :

Boiling point of ethanol is higher in comparison to methoxymethane.

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How are the following conversions carried out?

Benzyl chloride → Benzyl alcohol

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Give reasons for the following :

Phenol is more acidic than ethanol.

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When 3-methylbutan-2-ol is treated with HBr, the following reaction takes place:

Give a mechanism for this reaction.

(Hint : The secondary carbocation formed in step II rearranges to a more

stable tertiary carbocation by a hydride ion shift from 3rd carbon atom.

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Reference Material

Solution for concept: Physical and Chemical Properties of Alcohols and Phenols. For the courses 12th CBSE (Arts), 12th CBSE (Commerce), 12th CBSE (Science), PUC Karnataka Science
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