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Identify the weakest acidic compound amongst the following
(a) p-nitrophenol
(b) p-chlorophenol
(c) p-cresol
(d) p-raminophenol
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Solution
(d) p-Aminophenol
Electron-withdrawing substituents make the phenol more acidic, while electron-releasing substituents make the phenol less acidic. p-aminophenol < p-cresol < p-chlorophenol < p-nitrophenol
Concept: Phenols - Physical and Chemical Properties
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