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How Would You Explain the Lower Atomic Radius of Ga as Compared to Al? - Chemistry

How would you explain the lower atomic radius of Ga as compared to Al?

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Solution 1

Atomic radius (in pm)
Aluminium 143
Gallium 135

Although Ga has one shell more than Al, its size is lesser than Al. This is because of the poor shielding effect of the 3d-electrons. The shielding effect of d-electrons is very poor and the effective nuclear charge experienced by the valence electrons in gallium is much more than it is in the case of Al.

Solution 2

Due to poor shielding effect of d-electrons in Ga, the electrons in gallium experience great force of attraction by nucleus as compared to Al.

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NCERT Class 11 Chemistry Textbook
Chapter 11 The p-Block Elements
Q 24 | Page 324
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