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Give Reasons for the Following: E⁰ Value for (Mn3+|Mn2+) is Highly Positive than that for (Cr3+|Cr2+) Couple. - Chemistry

Short Note

Give reasons for the following:
The chemistry of actinoids elements is not so smooth as that of the lanthanoids.

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Solution

Lanthanoids primarily show three oxidation states (+2, +3, +4). Among these oxidation states, +3 state is the most common. Lanthanoids display a limited number of oxidation states because the energy difference between 4f, 5d, and 6s orbitals is quite large. On the other hand, the energy difference between 5f, 6d, and 7s orbitals is very less. 

Hence, actinoids display a large number of oxidation states. For example, uranium and plutonium display +3, +4, +5, and +6 oxidation states while neptunium displays +3, +4, +5, and +7. The most common oxidation state in the case of actinoids is also +3.

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