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Solution - Factors Influencing Rate of a Reaction

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What is pseudo first order reaction? Give one· example of it.

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The following results have been obtained during the kinetic studies of the reaction:

2A + B → C + D

Experiment A/ mol L−1 B/ mol L−1 Initial rate of formation of D/mol L−1 min−1
I 0.1 0.1 6.0 × 10−3
II 0.3 0.2 7.2 × 10−2
III 0.3 0.4 2.40 × 10−2
IV 0.4 0.1  

Determine the rate law and the rate constant for the reaction.

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For a reaction A + B ⟶ P, the rate is given by

Rate = k [A] [B]2

How is the rate of reaction affected if the concentration of B is doubled?

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A → B is a first order reaction with rate 6.6 × 10-5m-s-1. When [A] is 0.6m, rate constant of the reaction is

  • 1.1 × 10-5s-1
  • 1.1 × 10-4s-1
  • 9 × 10-5s-1
  • 9 × 10-4s-1
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For a reaction : 

(i) Write the order and molecularity of this reaction.

(ii) Write the unit of k.

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Define "zero order reaction".

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