State Kohlrausch law of independent migration of ions.
Kohlrausch law states as “The limiting molar conductivity of an electrolyte (i.e. molar conductivity at infinite dilution) is the sum of the limiting ionic conductivities of the cation and the anion each multiplied with the number of ions present in one formula unit of the electrolyte.
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- Conductance of Electrolytic Solutions - Variation of Conductivity and Molar Conductivity with Concentration