Complete the following reaction giving major products. CHX3.....|.......CHX3−C−CHX2−Cl→Na/dryether|.......CHX3..... - Chemistry

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Short Note

Complete the following reaction giving major products.

\[\begin{array}{cc}\ce{CH3\phantom{.....}}\\|\phantom{.......}\\\ce{CH3 - C - CH2 - Cl ->[Na/dry ether]}\\|\phantom{.......}\\
\ce{CH3\phantom{.....}}\end{array}\]

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Solution

\[\begin{array}{cc}
\ce{CH3\phantom{................................}}\ce{CH3\phantom{..............}}\ce{CH3\phantom{.......}}\\|\phantom{....................................}|\phantom{.................}|\phantom{.........}\\\ce{CH3 - C - CH2 - Cl + 2Na ->[dry ether] CH3 - C - CH2 - CH2 - C - CH3 + 2NaCl}\\|\phantom{....................................}|\phantom{..................}|\phantom{...........}\\\ce{\underset{\text{1-Chloro-2,2-dimethyl propane}}{CH3}\phantom{....}\phantom{..........}\underset{\text{2,2,5,5-Tetramethylhexane (A)}}{CH3}\phantom{...........}\ce{CH3}}\phantom{...................}
\end{array}\].

Concept: Preparation, Properties and Uses of Propane-1, 2, 3 Triol - Chemical Properties
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Balbharati Chemistry 12th Standard HSC for Maharashtra State Board
Chapter 10 Halogen Derivatives
Exercise | Q 2.5 | Page 232
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