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An Aromatic Organic Compound on Heating with Nh3 and Cu2o at High Pressure Gives , the Compound on Treatment with an Ice-cold So - Chemistry (Theory)

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ConceptAniline Sandmeyer’S Reaction

Question

An aromatic organic compound [A] on heating with NH3 and Cu2O at high pressure gives [B]. The compound [B] on treatment with the ice-cold solution of NaNO2 and HCI gives [C], which on heating with Cu/HCl gives compound [A] again. Identify the compounds [A], [B] and [C]. Write the name of the reaction for the conversion of [B] to [C].

Solution 1

This process is called diazotization. 

A – Chlorobenzene
B – Benzenamine or Aniline
C – Benzene diazonium chloride

Solution 2

Conversion of B to C is called Sand-Meyer reaction

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Solution An Aromatic Organic Compound on Heating with Nh3 and Cu2o at High Pressure Gives , the Compound on Treatment with an Ice-cold So Concept: Aniline - Sandmeyer’S Reaction.
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