A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is (i) doubled (ii) reduced to half?
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Solution
Letthe concentration of the reactant be [A] = a
Rate of reaction, R = k [A]2
= ka2
(i)If the concentration of the reactant is doubled, i.e. [A] = 2a, then the rate of the reaction would be R' = k(2a)2
= 4ka2
= 4 R
Therefore, the rate of the reaction would increase by 4 times.
(ii) If the concentration of the reactant is reduced to half, i.e. [A] = 1/2 a , then the rate of the reaction would be
`R' = k(1/2a)^2`
`=1/4ka^2`
`=1/4R`
Therefore, the rate of the reaction would be reduced to `1/4`th
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