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Tamil Nadu Board of Secondary EducationHSC Science इयत्ता १२

HSC Science इयत्ता १२ - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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A complex has a molecular formula \[\ce{MSO4Cl.6H2O}\] The aqueous solution of it gives white precipitate with Barium chloride solution and no precipitate is obtained when it is treated with silver nitrate solution. If the secondary valence of the metal is six, which one of the following correctly represents the complex?

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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As per IUPAC guidelines, the name of the complex [Co(en)2(ONO)Cl]Cl is

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Crystal field stabilization energy for high spin d5 octahedral complex is ____________.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Choose the correct statement.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Arrange the following in order of increasing molar conductivity.

i) \[\ce{Mg[Cr(NH3) (Cl)5]}\]

ii) \[\ce{[Cr(NH3)5 Cl]3 [CoF6]2}\]

iii) \[\ce{[Cr(NH3)3 Cl3]}\]

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Give an example for a complex of the type [Ma2b2c2] where a, b, c are monodentate ligands and give the possible isomers.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Give one test to differentiate \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]Cl}\].

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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In an octahedral crystal field, draw the figure to show the splitting of d orbitals.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Why tetrahedral complexes do not exhibit geometrical isomerism.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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What is crystal field stabilization energy (CFSE)?

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Discuss briefly the nature of bonding in metal carbonyls.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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What are the limitations of VB theory?

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Write the oxidation state, coordination number, nature of ligand, magnetic property and electronic configuration in octahedral crystal field for the complex \[\ce{K4[Mn(CN)6]}\].

[5] Coordination Chemistry
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The ratio of close packed atoms to tetrahedral hole in cubic packing is ____________.

[6] Solid State
Chapter: [6] Solid State
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A two-dimensional solid pattern formed by two different atoms X and Y is shown below. The black and white squares represent atoms X and Y respectively. the simplest formula for the compound based on the unit cell from the pattern is

[6] Solid State
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Distinguish between hexagonal close packing and cubic close packing.

[6] Solid State
Chapter: [6] Solid State
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Distinguish tetrahedral and octahedral voids.

[6] Solid State
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Explain AAAA and ABABA and ABCABC type of three dimensional packing with the help of neat diagram.

[6] Solid State
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Calculate the percentage efficiency of packing in the case of a body-centred cubic crystal.

[6] Solid State
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What is the two dimensional coordination number of a molecule in square close packed layer?

[6] Solid State
Chapter: [6] Solid State
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