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Tamil Nadu Board of Secondary EducationHSC Science इयत्ता १२

HSC Science इयत्ता १२ - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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What are transition metals? Give four examples.

[4] Transition and Inner Transition Elements
Chapter: [4] Transition and Inner Transition Elements
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Complete the following.

\[\ce{MnO^2-_4 + H^+ ->?}\]

[4] Transition and Inner Transition Elements
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What are interstitial compounds?

[4] Transition and Inner Transition Elements
Chapter: [4] Transition and Inner Transition Elements
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Calculate the number of unpaired electrons in Ti3+, Mn2+ and calculate the spin only magnetic moment.

[4] Transition and Inner Transition Elements
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Explain briefly how +2 states become more and more stable in the first half of the first-row transition elements with increasing atomic numbers.

[4] Transition and Inner Transition Elements
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Explain the variation in `"E"_ ("M"^(3+)//"M"^(2+))^0` 3d series.

[4] Transition and Inner Transition Elements
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Compare the ionization enthalpies of the first series of the transition elements.

[4] Transition and Inner Transition Elements
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The `"E"_("M"^(2+)//"M")^0` value for copper is positive. Suggest a possible reason for this.

[4] Transition and Inner Transition Elements
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Describe the variable oxidation state of 3d series elements.

[4] Transition and Inner Transition Elements
Chapter: [4] Transition and Inner Transition Elements
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Which metal in the 3d series exhibits +1 oxidation state most frequently and why?

[4] Transition and Inner Transition Elements
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Why first ionization enthalpy of chromium is lower than that of zinc?

[4] Transition and Inner Transition Elements
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Transition metals show high melting points why?

[4] Transition and Inner Transition Elements
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Oxidation state of Iron and the charge on the ligand NO in [Fe(H2O)5NO]SO4 are ____________.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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In which of the following coordination entities the magnitude of Δ0 will be maximum?

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Give an example of coordination compound used in medicine and two examples of biologically important coordination compounds.

[5] Coordination Chemistry
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Based on VB theory explain why \[\ce{[Cr(NH3)6]^3+}\] is paramagnetic, while \[\ce{[Ni(CN)4]^2-}\] is diamagnetic.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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[Ti(H2O)6]3+ is coloured, while [Sc(H2O)6]3+ is colourless – explain.

[5] Coordination Chemistry
Chapter: [5] Coordination Chemistry
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Classify the following ligand based on the number of donor atoms.

NH3

[5] Coordination Chemistry
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Classify the following ligand based on the number of donor atoms.

en

[5] Coordination Chemistry
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Classify the following ligand based on the number of donor atoms.

ox2−

[5] Coordination Chemistry
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