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Write the relationship between Gibbs energy change for a process and total entropy change of system and surroundings.
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Calculate the van't Hoff factor assuming the complete dissociation of NaBr in its aqueous solution.
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What is a spontaneous process? What are its characteristics?
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Calculate ΔTb and boiling point of 0.05 m aqueous solution of glucose. (Given: Kb = 0.52 K m−1).
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Write the mathematical equation between reaction rate constant and its activation energy.
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Calculate ΔG for ΔH = − 110 kJ, ΔS = + 40 J K−1 at 400 K.
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The value of van't Hoff factor will be minimum for ______.
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ΔH for the reaction is − 110 kJ, and ΔS is + 40 JK−1 at 400 K. The free energy change for the reaction is ______.
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Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.
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Explain with the help of Arrhenius equation, how does the rate of reaction changes with activation energy.
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For a certain reaction ΔH0 is −224 kJ and ΔS0 is −153 J K−1. At what temperature the change over from spontaneous to non-spontaneous will occur?
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Calculate ΔG0 for the reaction
\[\ce{CH_{4(g)} + H_{2(g)}-> C2H_{6(g)}}\]
State whether the reaction is spontaneous or not. (Given: KP = 3.358 × 1017, T = 25° C, R = 8.314 × 10−3 kJK−1 moI−1)
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Find out the value of equilibrium constant for the following reaction at 298 K, \[\ce{2NH3_{(g)} + CO2_{(g)} ⇌ NH2 - COONH2_{(aq)} + H2O_{(l)}}\] Gibbs Standard energy change 298 K = –13.6 kJ mol−1.
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Define second law of thermodynamics.
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Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.
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Explain with the help of Arrhenius equation, how does the rate of reaction changes with activation energy.
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Write the balanced chemical equations when acidified \[\ce{K2Cr2O7}\] reacts with \[\ce{H2S}\].
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Explain, with the help of the Arrhenius equation, how does the rate of reaction changes with temperature.
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Explain, with the help of the Arrhenius equation, how does the rate of reaction changes with activation energy.
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Explain with the help of Arrhenius equation, how does the rate of reaction changes with temperature.
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