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A substance crystallizes in fcc structure. The unit cell edge length is 367.8 pm. Calculate the molar mass of the substance if its density is 21.5 g/cm3.
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The following solution/solvent has maximum vapour pressure _______.
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According to Raoult’s law, relative lowering of vapour pressure of solution containing dissolved nonvolatile solute _______.
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Write the expression for relative lowering of vapour pressure.
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Observe the following compounds and answer the questions given below.

(I)
\[\ce{\underset{\text{(II)}}{CH3 - CH2 - Br}}\]
- Identify the type of halides.
- Explain the nature of the C – Br bond in both of these halides.
- Which of these compounds will undergo aqueous alkaline hydrolysis readily? Write the reaction in support of your answer.
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The vapour pressure of a pure liquid is 0.043 bar at a certain temperature. When a nonvolatile solute is dissolved into it, the vapour pressure of the solution is found to be 0.041 bar. What is the relative lowering of vapour pressure?
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For a very dilute solution, the osmotic pressure is given by π = n2RT/V where V is the volume in L containing n2 moles of nonvolatile solute. Establish the equation for molar mass of solute.
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Give two points to explain why vapour pressure of solvent is lowered by dissolving nonvolatile solute into it.
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NH4F is a salt of weak acid HF (Ka = 7.2 × 10–4) and weak base NH4OH (Kb = 1.8 × 10–5), the solution of NH4F will be ______.
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Give any one example of salt derived from weak acid and weak base.
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Define Hydrolysis of salt.
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Calculate the voltage of the cell Sn(s) / Sn2+(0.02 M) // Ag+ (0.01 M) / Ag(s) at 25 °C.
Given: `"E"_"Sn"^circ` = - 0.136, `"E"_"Ag"^circ` = 0.800 V
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Calculate `"E"_"cell"^circ` of the following galvanic cell:
Mg(s) / Mg2+(1 M) // Ag+ (1 M) / Ag(s) if `"E"_"Mg"^circ` = – 2.37 V and `"E"_"Ag"^circ` = 0.8 V. Write cell reactions involved in the above cell. Also mention if cell reaction is spontaneous or not.
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The reaction in which diazonium salt is used
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Write a balanced chemical reaction of sulfuric acid with carbon.
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Write a balanced chemical reaction of sulfuric acid with sulfur.
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What is the oxidation state of sulphur in the following?
Sulphurous acid
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Draw resonance structures of aryl diazonium salts.
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Write the use of aryl diazonium salts.
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