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Science (English Medium) इयत्ता ११ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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\[\ce{BF3}\] does not have proton but still acts as an acid and reacts with \[\ce{NH3}\]. Why is it so? What type of bond is formed between the two?

[6] Equilibrium
Chapter: [6] Equilibrium
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A reaction between ammonia and boron trifluoride is given below: \[\ce{NH3 + BF3 -> H3N : BF3}\] Identify the acid and base in this reaction. Which theory explains it? What is the hybridisation of B and N in the reactants?

[6] Equilibrium
Chapter: [6] Equilibrium
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Match the following species with the corresponding conjugate acid:

Species Conjugate acid
(i) \[\ce{NH3}\] (a) \[\ce{CO^{2-}3}\]
(ii) \[\ce{HCO^{-}3}\] (b) \[\ce{NH^{+}4}\]
iii) \[\ce{H2O}\] (c) \[\ce{H3O+}\]
(iv) \[\ce{HSO^{-}4}\] (d) \[\ce{H2SO4}\]
  (e) \[\ce{H2CO3}\]
[6] Equilibrium
Chapter: [6] Equilibrium
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Match the type of mixture of compounds in Column I with the technique of separation/purification given in Column II.

Column I Column II
(i) Two solids which have different solubilities in a solvent and which do not undergo reaction when dissolved in it. (a) Steam distillation
(ii) Liquid that decomposes at its boiling point (b) Fractional distillation
(iii) Steam volatile liquid (c) Simple distillation
(iv) Two liquids which have boiling points close to each other (d) Distillation under reduced pressure
(v) Two liquids with large difference in boiling points. (e) Crystallisation
[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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Assertion (A): Simple distillation can help in separating a mixture of propan-1-ol (boiling point 97°C) and propanone (boiling point 56°C).

Reason (R): Liquids with a difference of more than 20°C in their boiling points can be separated by simple distillation.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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Two liquids (A) and (B) can be separated by the method of fractional distillation. The boiling point of liquid (A) is less than boiling point of liquid (B). Which of the liquids do you expect to come out first in the distillate? Explain.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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Draw a diagram of bubble plate type fractionating column. When do we require such type of a column for separating two liquids. Explain the principle involved in the separation of components of a mixture of liquids by using fractionating column. What industrial applications does this process have?

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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Arrange the following carbanions in order of their decreasing stability.

(A) H3C – C ≡ C

(B) H – C ≡ C

(C) \[\ce{H3C - C\overset{-}{H2}}\]

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Which of the following are correct?

(i) \[\ce{CH3 - O - CH^{⊕}2}\] is more stable than \[\ce{CH3 - CH^{⊕}2}\]

(ii) (CH3)2CH is less stable than \[\ce{CH3 - CH2 - CH^{⊕}2}\]

(iii) \[\ce{CH3 = CH2 - CH^{⊕}2}\] is more stable than \[\ce{CH3 - CH2 - CH^{⊕}2}\]

(iv) \[\ce{CH2 - CH^{⊕}}\] is more stable than \[\ce{CH3 - CH^{⊕}2}\]

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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How will you convert benzene into p – nitrobromobenzene

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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How will you convert benzene into m – nitrobromobenzene

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Arrange the following set of compounds in the order of their decreasing relative reactivity with an electrophile. Give reason.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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The relative reactivity of 1°, 2°, 3° hydrogen’s towards chlorination is 1 : 3.8 : 5. Calculate the percentages of all monochlorinated products obtained from 2-methylbutane.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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The bromine atom possesses 35 electrons. It contains 6 electrons in 2p orbital, 6 electrons in 3p orbital and 5 electrons in 4p orbital. Which of these electron experiences the lowest effective nuclear charge?

[2] Structure of Atom
Chapter: [2] Structure of Atom
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Among the following pairs of orbitals which orbital will experience the larger effective nuclear charge?

  1. 2s and 3s,
  2. 4d and 4f,
  3. 3d and 3p
[2] Structure of Atom
Chapter: [2] Structure of Atom
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Write the significance of a plus and a minus sign shown in representing the orbitals.

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
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A reaction, A + B → C + D + q is found to have a positive entropy change. The reaction will be ______.

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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For the reaction, \[\ce{2Cl_{(g)} → Cl_{2(g)}}\], what are the signs of ΔH and ΔS?

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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What are the necessary conditions for any system to be aromatic?

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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Explain why the following system is not aromatic?

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
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