Advertisements
Advertisements
Electronic configuration of some elements is given in Column I and their electron gain enthalpies are given in Column II. Match the electronic configuration with electron gain enthalpy.
| Column (I) | Column (II) |
| Electronic configuration | Electron gain enthalpy/kJ mol–1 |
| (i) 1s2 2s2 sp6 | (A) – 53 |
| (ii) 1s2 2s2 2p6 3s1 | (B) – 328 |
| (iii) 1s2 2s2 2p5 | (C) – 141 |
| (iv) 1s2 2s2 2p4 | (D) + 48 |
Concept: undefined >> undefined
Assertion (A): Boron has a smaller first ionisation enthalpy than beryllium.
Reason (R): The penetration of a 2s electron to the nucleus is more than the 2p electron hence 2p electron is more shielded by the inner core of electrons than the 2s electrons.
Concept: undefined >> undefined
Advertisements
Assertion (A): Electron gain enthalpy becomes less negative as we go down a group.
Reason (R): Size of the atom increases on going down the group and the added electron would be farther from the nucleus.
Concept: undefined >> undefined
Discuss the factors affecting electron gain enthalpy and the trend in its variation in the periodic table.
Concept: undefined >> undefined
Stable form of A may be represented by the formula:
Concept: undefined >> undefined
Explain the non-linear shape of \[\ce{H2S}\] and non-planar shape of \[\ce{PCl3}\] using valence shell electron pair repulsion theory.
Concept: undefined >> undefined
Elements \[\ce{X, Y}\] and \[\ce{Z}\] have 4, 5 and 7 valence electrons respectively. Write the molecular formula of the compounds formed by these elements individually with hydrogen.
Concept: undefined >> undefined
Elements \[\ce{X, Y}\] and \[\ce{Z}\] have 4, 5 and 7 valence electrons respectively. Which of these compounds will have the highest dipole moment?
Concept: undefined >> undefined
Which of the following figures does not represent 1 mole of dioxygen gas at STP?
(i) 16 grams of gas
(ii) 22.7 litres of gas
(iii) 6.022 × 1023 dioxygen molecules
(iv) 11.2 litres of gas
Concept: undefined >> undefined
What will be the molar volume of nitrogen and argon at 273.15 K and 1 atm?
Concept: undefined >> undefined
\[\ce{PCl5, PCl3 and Cl2}\] are at equilibrium at 500 K in a closed container and their concentrations are 0.8 × 10–3 mol L–1, 1.2 × 10–3 mol L–1 and 1.2 × 10–3 mol L–1 respectively. The value of Kc for the reaction \[\ce{PCl5 (g) ⇌ PCl3 (g) + Cl2 (g)}\] will be ______.
Concept: undefined >> undefined
\[\ce{pH}\] of a solution of a strong acid is 5.0. What will be the \[\ce{pH}\] of the solution obtained after diluting the given solution a 100 times?
Concept: undefined >> undefined
Calculate the \[\ce{pH}\] of a solution formed by mixing equal volumes of two solutions A and B of a strong acid having \[\ce{pH}\] = 6 and \[\ce{pH}\] = 4 respectively.
Concept: undefined >> undefined
Match the following graphical variation with their description
| A | B |
(i) ![]() |
(a) Variation in product concentration with time |
(ii) ![]() |
(b) Reaction at equilibrium |
(iii) ![]() |
(c) Variation in reactant concentration with time |
Concept: undefined >> undefined
The oxide that gives \[\ce{H2O2}\] on treatment with dilute \[\ce{H2SO4}\] is ______.
Concept: undefined >> undefined
When sodium peroxide is treated with dilute sulphuric acid, we get ______.
Concept: undefined >> undefined
Which of the following ions will cause hardness in water sample?
Concept: undefined >> undefined
Which of the following compounds is used for water softening?
Concept: undefined >> undefined
Hardness of water may be temporary or permanent. Permanent hardness is due to the presence of:
(i) Chlorides of \[\ce{Ca}\] and \[\ce{Mg}\] in water.
(ii) Sulphates of \[\ce{Ca}\] and \[\ce{Mg}\] in water.
(iii) Hydrogen carbonates of \[\ce{Ca}\] and \[\ce{Mg}\] in water.
(iv) Carbonates of alkali metals in water.
Concept: undefined >> undefined
Complete the following equations:
\[\ce{PbS (s) + H2O2 (aq) ->}\]
Concept: undefined >> undefined



