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Science (English Medium) इयत्ता ११ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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What is the correct order of decreasing stability of the following cations.

I. \[\ce{CH3 - \overset{⊕}{C}H - CH3}\]
II. \[\ce{CH3 - \overset{⊕}{C}H - OCH3}\]
III. \[\ce{CH3 - \overset{⊕}{C}H - CH2 - OCH3}\]
[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
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Covalent bond can undergo fission in two different ways. The correct representation involving a heterolytic fission of CH3 – Br is:

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
Concept: undefined >> undefined

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Write structures of various carbocations that can be obtained from 2-methylbutane. Arrange these carbocations in order of increasing stability.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
Concept: undefined >> undefined

Match the intermediates given in Column I with their probable structure in Column II.

Column I Column II
(i) Free radical (a) Trigonal planar
(ii) Carbocation (b) Pyramidal
(iii) Carbanion (c) Linear
[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
Concept: undefined >> undefined

Which of the following practices will not come under green chemistry?

[14] Environmental Chemistry
Chapter: [14] Environmental Chemistry
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An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

An alkene ‘A’ contains three C–C, eight C–H σ bonds and one C–C π bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

The following data are obtained when dinitrogen and dioxygen react together to form different compounds:-

  Mass of dinitrogen Mass of dioxygen
(i) 14 g 16 g
(ii) 14 g 32 g
(iii) 28 g 32 g
(iv) 28 g 80 g

(a) Which law of chemical combination is obeyed by the above experimental data?Give its statement.

(b) Fill in the blanks in the following conversions:

(i) 1 km = ______ mm = ______ pm

(ii) 1 mg = ______ kg = ______ ng

(iii) 1 mL = ______ L = _______ dm3

[1] Some Basic Concepts of Chemistry
Chapter: [1] Some Basic Concepts of Chemistry
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How do you express the bond strength in terms of bond order?

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
Concept: undefined >> undefined

Compare the relative stability of the following species and indicate their magnetic properties;

`"O"_2, "O"_2^+, "O"_2^-`(superoxide), `"O"_2^(2-)`(peroxide)

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
Concept: undefined >> undefined

Calculate the bond order of N2, O2, `"O"_2^+`and `"O"_2^-`?

[4] Chemical Bonding and Molecular Structure
Chapter: [4] Chemical Bonding and Molecular Structure
Concept: undefined >> undefined

Write IUPAC name of the product obtained by the ozonolysis of the following compound:

3,4-Dimethyl-hept-3-ene

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

Write IUPAC name of the product obtained by the ozonolysis of the following compound:

2-Ethylbut-1-ene 

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

What effect does branching of an alkane chain has on its boiling point?

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

One of the reactions that takes place in producing steel from iron ore is the reduction of iron (II) oxide by carbon monoxide to give iron metal and CO2.

\[\ce{FeO (s) + CO (g) ↔ Fe (s) + CO2 (g)}\]; Kp= 0.265 at 1050 K.

What are the equilibrium partial pressures of CO and CO2 at 1050 K if the initial partial pressures are: pCO = 1.4 atm and `"p"_("co"_2)`= 0.80 atm?

[6] Equilibrium
Chapter: [6] Equilibrium
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What are electrophiles and nucleophiles? Explain with examples.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
Concept: undefined >> undefined

Identify the reagents shown in bold in the following equation as nucleophiles or electrophiles:

\[\ce{C6H6 + \underline{\text{CH}_3\overset{+}{\ce{C}}{\ce{O}}} -> C6H5COCH3}\]

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
Concept: undefined >> undefined

What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?

\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{H}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{D}
\end{array}\]

\[\begin{array}{cc}
\ce{D}\phantom{......}\ce{D}\\
\backslash\phantom{......}/\\
\ce{C = C}\\
\phantom{...}/\phantom{......}\backslash\phantom{...}\\\ce{H}\phantom{.......}\ce{H}\end{array}\]

[9] Hydrocarbons
Chapter: [9] Hydrocarbons
Concept: undefined >> undefined

The reaction: \[\ce{CH_3CH_2I + KOH_{(aq)} -> CH_3CH_2OH + KI}\] is classified as ______.

[8] Organic Chemistry - Some Basic Principles and Techniques
Chapter: [8] Organic Chemistry - Some Basic Principles and Techniques
Concept: undefined >> undefined
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