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Science (English Medium) इयत्ता ११ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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Assertion (A): Combustion of 16 g of methane gives 18 g of water.

Reason (R): In the combustion of methane, water is one of the products.

[1] Some Basic Concepts of Chemistry
Chapter: [1] Some Basic Concepts of Chemistry
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A vessel contains 1.6 g of dioxygen at STP (273.15K, 1 atm pressure). The gas is now transferred to another vessel at constant temperature, where pressure becomes half of the original pressure. Calculate volume of the new vessel.

[1] Some Basic Concepts of Chemistry
Chapter: [1] Some Basic Concepts of Chemistry
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The first ionisation enthalpies of \[\ce{Na, Mg, Al}\] and \[\ce{Si}\] are in the order:

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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The period number in the long form of the periodic table is equal to ______.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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In the modern periodic table, elements are arranged in order of increasing atomic numbers which is related to the electronic configuration. Depending upon the type of orbitals receiving the last electron, the elements in the periodic table have been divided into four blocks, viz, s, p, d and f. The modern periodic table consists of 7 periods and 18 groups. Each period begins with the filling of a new energy shell. In accordance with the Arfbau principle, the seven periods have 2, 8, 8, 18, 18, 32 and 32 elements respectively. The seventh period is still incomplete. To avoid the periodic table being too long, the two series of f-block elements, called lanthanoids and actinoids are placed at the bottom of the main body of the periodic table.

The electronic configuration of the element which is just above the element with atomic number 43 in the same group is ______.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Which of the following sets contain only isoelectronic ions?

(i) \[\ce{Zn^{2+}, Ca^{2+}, Ga^{3+}, Al^{3+}}\]

(ii) \[\ce{K+ , Ca^{2+}, Sc^{3+}, Cl-}\]

(iii) \[\ce{P^{3-}, S^{2-}, Cl- , K+}\]

(iv) \[\ce{Ti^{4+}, Ar, Cr^{3+}, V^{5+}}\]

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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An element belongs to 3rd period and group-13 of the periodic table. Which of the following properties will be shown by the element?

(i) Good conductor of electricity

(ii) Liquid, metallic

(iii) Solid, metallic

(iv) Solid, non metallic

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Identify the group and valency of the element having atomic number 119. Also predict the outermost electronic configuration and write the general formula of its oxide.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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How would you explain the fact that first ionisation enthalpy of sodium is lower than that of magnesium but its second ionisation enthalpy is higher than that of magnesium?

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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How does the metallic and non-metallic character vary on moving from left to right in a period?

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Justify the given statement with suitable examples— “the Properties of the elements are a periodic function of their atomic numbers”.

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Write down the outermost electronic configuration of alkali metals. How will you justify their placement in group 1 of the periodic table?

[3] Classification of Elements and Periodicity in Properties
Chapter: [3] Classification of Elements and Periodicity in Properties
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Use the information and data given below:

• Boiling point of \[\ce{HF, HCl, HBr and HI}\] are 293 K, 189 K, 206 K and 238 K respectively.

Why is boiling point of hydrogen fluoride highest while that of hydrogen chloride lowest?

[5] States of Matter:- Gases and Liquids
Chapter: [5] States of Matter:- Gases and Liquids
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Thermodynamics is not concerned about ______.

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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Thermodynamics mainly deals with:

(i) interrelation of various forms of energy and their transformation from one form to another.

(ii) energy changes in the processes which depend only on initial and final states of the microscopic systems containing a few molecules.

(iii) how and at what rate these energy transformations are carried out.

(iv) the system in equilibrium state or moving from one equilibrium state to another equilibrium state.

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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Consider the following reaction between zinc and oxygen and choose the correct options out of the options given below:

\[\ce{2 Zn (s) + O2 (g) -> 2 ZnO (s); ∆H = - 693.8 kJ mol^{-1}}\]

(i) The enthalpy of two moles of \[\ce{ZnO}\] is less than the total enthalpy of two moles of \[\ce{Zn}\] and one mole of oxygen by 693.8 kJ.

(ii) The enthalpy of two moles of \[\ce{ZnO}\] is more than the total enthalpy of two moles of \[\ce{Zn}\] and one mole of oxygen by 693.8 kJ.

(iii) 693.8 kJ mol–1 energy is evolved in the reaction.

(iv) 693.8 kJ mol–1 energy is absorbed in the reaction.

[5] Chemical Thermodynamics
Chapter: [5] Chemical Thermodynamics
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Which of the following is not an example of redox reaction?

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Identify disproportionation reaction

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Which of the following elements does not show disproportionation tendency?

[7] Redox Reactions
Chapter: [7] Redox Reactions
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Which of the following statement(s) is/are not true about the following decomposition reaction.

\[\ce{2KClO3 -> 2KCl + 3O2}\]

(i) Potassium is undergoing oxidation.

(ii) Chlorine is undergoing oxidation.

(iii) Oxygen is reduced.

(iv) None of the species are undergoing oxidation or reduction.

[7] Redox Reactions
Chapter: [7] Redox Reactions
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