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Tamil Nadu Board of Secondary EducationHSC Science कक्षा १२

HSC Science कक्षा १२ - Tamil Nadu Board of Secondary Education Question Bank Solutions for Chemistry

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Chemistry
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The pH of an aqueous solution is Zero. The solution is ____________.

[8] Ionic Equilibrium
Chapter: [8] Ionic Equilibrium
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The concentration of hydroxide ion in a water sample is found to be 2.5 × 10−6 M. Identify the nature of the solution.

[8] Ionic Equilibrium
Chapter: [8] Ionic Equilibrium
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A lab assistant prepared a solution by adding a calculated quantity of HCl gas at 25°C to get a solution with [H3O+]= 4 × 10−5 M. Is the solution neutral (or) acidic (or) basic.

[8] Ionic Equilibrium
Chapter: [8] Ionic Equilibrium
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Calculate the pH of 0.04 M HNO3 solution.

[8] Ionic Equilibrium
Chapter: [8] Ionic Equilibrium
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Calculate the pH of 1.5 × 10−3 M solution of Ba(OH)2.

[8] Ionic Equilibrium
Chapter: [8] Ionic Equilibrium
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50 ml of 0.05 M HNO3 is added to 50 ml of 0.025 M KOH. Calculate the pH of the resultant solution.

[8] Ionic Equilibrium
Chapter: [8] Ionic Equilibrium
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The Ka value for HCN is 10−9. What is the pH of 0.4 M HCN solution?

[8] Ionic Equilibrium
Chapter: [8] Ionic Equilibrium
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Consider the following half cell reactions:

\[\ce{Mn^{2+} + 2e^- -> Mn}\] E0 = –1.18 V

\[\ce{Mn^{2+} -> Mn^{2+} + e^-}\] E0 = –1.51 V

The E0 for the reaction \[\ce{3Mn^{2+} -> Mn + 2Mn^{3+}}\], and the possibility of the forward reaction are respectively.

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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The button cell used in watches functions as follows.

\[\ce{Zn_{(s)} + Ag2O_{(s)} + H2O_{(l)} ⇌ 2Ag_{(s)} + Zn^{2+}_{( aq)} + 2OH^-_{( aq)}}\] the half cell potentials are \[\ce{Ag2O_{(s)} + H2O_{(l)} + 2e^- -> 2Ag_{(s)} + 2OH^-_{( aq)}}\] E0 = 0.34 V The cell potential will be

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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During electrolysis of molten sodium chloride, the time required to produce 0.1 mole of chlorine gas using a current of 3A is ___________.

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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The number of electrons delivered at the cathode during electrolysis by a current of 1A in 60 seconds is ____________.
(charge of electron = 1.6 × 10−19 C)

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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While charging lead storage battery

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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Among the following cells

I) Leclanche cell

II) Nickel – Cadmium cell

III) Lead storage battery

IV) Mercury cell

Primary cells are:

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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In \[\ce{H2 - O2}\] fuel cell the reaction occurs at cathode is:

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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For the cell reaction

\[\ce{2Fe^{3+}_{( aq)} + 2l^-_{( aq)} -> 2Fe^{2+}_{( aq)} + l2_{( aq)}}\]

\[\ce{E^0_{cell}}\] = at 298 K. The standard Gibbs energy (∆G°) of the cell reactions is:

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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State Faraday’s Laws of electrolysis.

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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A current of 1.608A is passed through 250 mL of 0.5 M solution of copper sulphate for 50 minutes. Calculate the strength of Cu2+ after electrolysis assuming volume to be constant and the current efficiency is 100%.

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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Calculate the standard emf of the cell: \[\ce{Cd|Cd^{2+}||Cu^{2+}|Cu}\] and determine the cell reaction. The standard reduction potentials of Cu2+|Cu and Cd2+|Cd are 0.34 V and −0.40 volts respectively. Predict the feasibility of the cell reaction.

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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In fuel cell H2 and O2 react to produce electricity. In the process, H2 gas is oxidised at the anode and O2 at cathode. If 44.8 litre of H2 at 25°C and 1 atm pressure reacts in 10 minutes, what is average current produced? If the entire current is used for electro deposition of Cu from Cu2+, how many grams of deposited?

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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The same amount of electricity was passed through two separate electrolytic cells containing solutions of nickel nitrate and chromium nitrate respectively. If 2.935 g of Ni was deposited in the first cell. The amount of Cr deposited in the another cell?
Given: molar mass of Nickel and chromium are 58.74 and 52 gm−1 respectively.

[9] Electro Chemistry
Chapter: [9] Electro Chemistry
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