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MAH-MHT CET (PCM/PCB) entrance exam Question Bank Solutions for Chemistry

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Chemistry
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Identify the compound having highest boiling point from the following?

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
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Xenon crystallizes in fee lattice and the edge length of unit cell is 620 pm. What is the radius of Xe atom?

[11] Solid State
Chapter: [11] Solid State
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Identify the role of PDC from the following.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
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Identify the product X in the following reaction.

\[\ce{Phenol ->[Na2Cr2O7][H2SO4] X}\]

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
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The edge length of bcc type of unit cell of metal is 5 Å. What is the radius of metal atom if it's density is 2 glee?

[11] Solid State
Chapter: [11] Solid State
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Henry's law is a relation between ______.

[12] Solutions
Chapter: [12] Solutions
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How many gram of water is decomposed by 429 kJ of heat if heat of decomposition of water is 286 kJ mol-1?

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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If \[\ce{C_{(s)} + O_{2(g)} -> CO_{2(g)}}\], ΔH = - 396 kJ mol-1, calculate heat liberated during formation of 0.154 kg of CO2.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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The molar heat capacity of water at constant pressure is 75 JK−1 mol−1. When 1 kJ of heat is supplied to 100 g of water, which is free to expand, the increase in temperature of the water is ______.

[14] Chemical Thermodynamics
Chapter: [14] Chemical Thermodynamics
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The compound which reacts fastest with Lucas reagent at room temperature is ______.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
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According to the Le-Chatelier principle, adding heat to a solid \[\ce{<=>}\] liquid equilibrium will cause the ______.

[12] Solutions
Chapter: [12] Solutions
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Which one of the following is Swartz reaction?

[20] Halogen Derivatives
Chapter: [20] Halogen Derivatives
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Henry’s law constant of oxygen is 1.4 × 10–3 mol lit–1 atm–1 at 298 K. How much of oxygen is dissolved in 100 ml at 298 K when the partial pressure of oxygen is 0.5 atm?

[12] Solutions
Chapter: [12] Solutions
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The reaction takes place in two steps as

(i) \[\ce{NO2Cl(g) ->[k1] NO2(g) + Cl(g)}\]

(ii) \[\ce{NO2Cl(g) + Cl(g) ->[k2] NO2(g) + Cl2(g)}\]

Identify the reaction intermediate.

[16] Chemical Kinetics
Chapter: [16] Chemical Kinetics
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Which among the following phenolic compound is most acidic in nature?

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
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The solubility (in mol L−1) of AgCl (Ksp = 1.0 × 10−10) in a 0.1 M KCl solution will be ______.

[12] Solutions
Chapter: [12] Solutions
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Name the catalyst used in commercial method of preparation of phenol.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
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Electrode potentials (E0) are given below:

Cu+/Cu = + 0.52 V,

Fe3+/Fe2+ = + 0.77 V,

\[\ce{1/2I2(s)/I^-}\] = + 0.54 V,

Ag+/Ag = + 0.88 V

Based on the above potentials, the strongest oxidizing agent will be:

[4] Redox Reactions
Chapter: [4] Redox Reactions
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The number of molecules in 8.96 litres of gas at 0°C and 1 atm. pressure is approximately ______.

[6] States of Matter: Gaseous and Liquid States
Chapter: [6] States of Matter: Gaseous and Liquid States
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Identify the compound amongst the following of which 0.1 M aqueous solution has highest boiling point.

[21] Alcohols, Phenols, and Ethers
Chapter: [21] Alcohols, Phenols, and Ethers
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