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Explain why propanol has higher boiling point than that of the hydrocarbon, butane?
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Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses. Explain this fact.
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Give reason for the higher boiling point of ethanol in comparison to methoxymethane.
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Arrange the set of compounds in order of increasing boiling points.
Bromomethane, Bromoform, Chloromethane, Dibromomethane.
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Arrange the set of compounds in order of increasing boiling points.
1-Chloropropane, Isopropyl chloride, 1-Chlorobutane.
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Explain why alkyl halides, though polar, are immiscible with water?
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p-Dichlorobenzene has higher m.p. and lower solubility than those of o- and m-isomers. Discuss.
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Give simple chemical tests to distinguish between the following pairs of compounds :
Ethanol and phenol
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Write one similarity and one difference between the chemistry of lanthanoid and actinoid elements.
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What is the effect of adding a catalyst on Activation energy (Ea)
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Arrange the following compounds in the increasing order of their acid strength:
p-cresol, p-nitrophenol, phenol
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The cell in which the following reaction occurs:
`2Fe^(3+) (aq) + 2I^(-) (aq) ---> 2Fe^(2+) (aq) + I_2 (s)` has `E_"cell"^@` = 0.236 V at 298 K. Calculate the standard Gibbs energy of the cell reaction. (Given : 1 F = 96,500 C mol−1)
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A first-order reaction is 50% completed in 40 minutes at 300 K and in 20 minutes at 320 K. Calculate the activation energy of the reaction. (Given : log 2 = 0·3010, log 4 = 0·6021, R = 8·314 JK–1 mol–1)
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Identify the chiral molecule in the following pair :

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Write the structures of the main products of the following reactions:

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Write the structures of the main products of the following reactions:

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Write the structures of the main products of the following reactions:

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How would you account the following :
Highest fluoride of Mn is MnF4 whereas the highest oxide is Mn2O7.
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Write the structures of A, B and C in the following reactions :
\[ C_6 H_5 {NO}_2 \to^{Sn/HCI} A \to^{{NaNO}_2 /HCI}_{273 K} B \to^{H_2 O}_∆ C\]
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How do you prepare:
Actinoid elements show wide range of oxidation states.
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