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The molecular formula of the compound formed from \[\ce{B}\] and \[\ce{C}\] will be ______.
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The electronic configuration of the outer most shell of the most electronegative element is ______.
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Amongst the following elements whose electronic configurations are given below, the one having the highest ionisation enthalpy is ______.
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Dimagnetic species are those which contain no unpaired electrons. Which among the following are dimagnetic?
(i) \[\ce{N2}\]
(ii) \[\ce{N^{2-}2}\]
(iii) \[\ce{O2}\]
(iv) \[\ce{O^{2-}2}\]
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Explain the shape of \[\ce{BrF5}\].
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Explain why \[\ce{PCl5}\] is trigonal bipyramidal whereas \[\ce{IF5}\] is square pyramidal.
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Which of the following statements is correct?
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In DNA and RNA, nitrogen atom is present in the ring system. Can Kjeldahl method be used for the estimation of nitrogen present in these? Give reasons.
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Match Column I with Column II.
| Column I | Column II |
| (i) Dumas method | (a) AgNO3 |
| (ii) Kjeldahl’s method | (b) Silica gel |
| (iii) Carius method | (c) Nitrogen gas |
| (iv) Chromatography | (d) Free radicals |
| (v) Homolysis | (e) Ammonium sulphate |
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Which of the following reactions of methane is incomplete combustion:
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The intermediate carbocation formed in the reactions of HI, HBr and HCl with propene is the same and the bond energy of HCl, HBr and HI is 430.5 kJ mol–1, 363.7 kJ mol–1 and 296.8 kJ mol–1 respectively. What will be the order of reactivity of these halogen acids?
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Predict the major product (s) of the following reactions and explain their formation.
\[\ce{H3C - CH = CH2 ->[(Ph.CO.O)2][HBr]}\]
\[\ce{H3C - CH = CH2 ->[HBr]}\]
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Nucleophiles and electrophiles are reaction intermediates having electron-rich and electron-deficient centres respectively. Hence, they tend to attack electron-deficient and electron-rich centres respectively. Classify the following species as electrophiles and nucleophiles.
(i) H3CO–
(ii) \[\begin{array}{cc}
\phantom{.}\ce{O}\\
\phantom{.}||\\
\ce{H3C - C - O-}
\end{array}\]
(iii) \[\ce{\overset{\bullet}{C}l}\]
(iv) Cl2C:
(v) (H3C)3C+
(vi) Br–
(vii) H3COH
(viii) R – NH – R
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Write hydrocarbon radicals that can be formed as intermediates during monochlorination of 2-methylpropane? Which of them is more stable? Give reasons.
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0.3780 g of an organic chloro compound gave 0.5740 g of silver chloride in Carius estimation. Calculate the percentage of chlorine present in the compound.
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In the estimation of sulphur by Carius method, 0.468 g of an organic sulphur compound afforded 0.668 g of barium sulphate. Find out the percentage of sulphur in the given compound.
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Discuss the principle of estimation of halogens present in an organic compound.
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\[\ce{CO}\] is isoelectronic with
(i) \[\ce{NO+}\]
(ii) \[\ce{N2}\]
(iii) \[\ce{Sncl2}\]
(iv) \[\ce{NO^{-}2}\]
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Give reasons for the following:
Ethyne molecule is linear.
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Assertion (A): Among the two \[\ce{O - H}\] bonds in \[\ce{H2O}\] molecule, the energy required to break the first \[\ce{O - H}\] bond and the other \[\ce{O - H}\] bond is the same.
Reason (R): This is because the electronic environment around oxygen is the same even after breakage of one \[\ce{O - H}\] bond.
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