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activation energy, most probable kinetic energy, Effect of Catalyst
The decomposition of hydrocarbon follows the equation k = (4.5 × 1011 s−1) e−28000 K/T
The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the energy of activation of the reaction assuming that it does not change with temperature.
The rate constant for the first order decomposition of H2O2 is given by the following equation:
log k = 14.34 − 1.25 × 104 K/T
Calculate Ea for this reaction and at what temperature will its half-period be 256 minutes?
In the Arrhenius equation for a first order reaction, the values of ‘A’ of ‘Ea’ are 4 x 1013 sec-1 and 98.6 kJ mol-1 respectively. At what temperature will its half life period be 10 minutes?
[R = 8.314 J K-1 mol-1]
The activation energy for the reaction 2HI(g) → H2 + I2(g) is 209.5 kJ mol−1 at 581K. Calculate the fraction of molecules of reactants having energy equal to or greater than activation energy?
The rate constant for the decomposition of N2O5 at various temperatures is given below:
Draw a graph between ln k and 1/T and calculate the values of A and Ea. Predict the rate constant at 30º and 50ºC.
Consider the reaction-
At particular time t, `(d[SO_4^(2-)])/dt=2.2xx10^(-2)"m/s"`
What are the values of the following at the same time?
The decomposition of A into product has value of k as 4.5 × 103 s−1 at 10°C and energy of activation 60 kJ mol−1. At what temperature would k be 1.5 × 104 s−1?
The rate constant for the decomposition of hydrocarbons is 2.418 × 10−5 s−1 at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of pre-exponential factor.
(b) Rate constant ‘k’ of a reaction varies with temperature ‘T’ according to the equation:
Where Ea is the activation energy. When a graph is plotted for `logk Vs. 1/T` a straight line with a slope of −4250 K is obtained. Calculate ‘Ea’ for the reaction.(R = 8.314 JK−1 mol−1)
The rate constant of a first order reaction increases from 4 × 10−2 to 8 × 10−2 when the temperature changes from 27°C to 37°C. Calculate the energy of activation (Ea). (log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
The rate constant of a first order reaction increases from 2 × 10−2 to 4 × 10−2 when the temperature changes from 300 K to 310 K. Calculate the energy of activation (Ea).
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
The rate constant for the first-order decomposition of H2O2 is given by the following equation:
Calculate Ea for this reaction and rate constant k if its half-life period be 200 minutes.
(Given: R = 8.314 JK–1 mol–1)