A first order reaction takes 23.1 minutes for 50% completion. Calculate the time required for 75% completion of this reaction.
(log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
The experimental data for decomposition of N2O5
[`2N_2O_5 -> 4NO_2 + O_2`] in gas phase at 318K are given below:
(i) Plot [N2O5] against t.
(ii) Find the half-life period for the reaction.
(iii) Draw a graph between log [N2O5] and t.
(iv) What is the rate law?
(v) Calculate the rate constant.
(vi) Calculate the half-life period from k and compare it with (ii).
A first order reaction takes 30 minutes for 50% completion. Calculate the time required for 90% completion of this reaction.
(log 2 = 0.3010)
The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80% of the 14C found in a living tree. Estimate the age of the sample.
During nuclear explosion, one of the products is 90Sr with half-life of 28.1 years. If 1μg of 90Sr was absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after 10 years and 60 years if it is not lost metabolically.
Sucrose decomposes in acid solution to give glucose and fructose according to the first order rate law. The half life of the reaction is 3 hours. Calculate fraction of sucrose which will remain after 8 hours.
A first order reaction takes 40 minutes for 30% decomposition. Calculate t1/2 for this reaction. (Given log 1.428 = 0.1548)
Calculate the half-life of a first order reaction from their rate constants given below:
(i) 200 s−1 (ii) 2 min−1 (iii) 4 years−1